Optimization of the solvent on the condensation of dimedone, benzaldehyde, and 4-hydroxycoumarin using a green LED (25 W)a.
| Entry | WO3/ZnO@NH2-EY (g) | Solvent | Time (min) | Yield (%) |
|---|---|---|---|---|
| 1 | 0.03 | — | 45 | 97 |
| 2 | 0.03 | H2O | 180 | 45 |
| 3 | 0.03 | Toluene | 180 | 62 |
| 4 | 0.03 | Ethanol | 180 | 77 |
| 5 | 0.03 | CH3CN | 180 | 95 |
Reaction conditions are described below Table 1. 3 mL solvent was used.