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. 2021 May 26;11(31):19029–19040. doi: 10.1039/d1ra01377g

Substituents used in this study and their corresponding Hammett constants,90,91σp. The empirically derived Hammett constant (σp) is used to quantify the strength in which a substituent is electron withdrawing (positive) or electron donating (negative).

Substituent Hammett constant (σp) Classification
N(CH3)2 −0.83 Donating
CH3 −0.17
H 0
Cl 0.23 Withdrawing
NO2 0.78