Substituents used in this study and their corresponding Hammett constants,90,91σp. The empirically derived Hammett constant (σp) is used to quantify the strength in which a substituent is electron withdrawing (positive) or electron donating (negative).
Substituent | Hammett constant (σp) | Classification |
---|---|---|
N(CH3)2 | −0.83 | Donating |
CH3 | −0.17 | |
H | 0 | |
Cl | 0.23 | Withdrawing |
NO2 | 0.78 |