1H and 13C NMR data (400 MHz for 1H, and 100 MHz for 13C) of compound 10a.
| Position | 10b | |
|---|---|---|
| δ H | δ C | |
| 1 | 129.8 | |
| 2 | 7.06 s | 110.1 |
| 3 | 145.0 | |
| 4 | 141.9 | |
| 4a | 117.1 | |
| 4b | 127.3 | |
| 5 | 8.80 d (9.2) | 123.7 |
| 6 | 7.28 d (9.2) | 112.7 |
| 7 | 149.9 | |
| 8 | 143.2 | |
| 8a | 123.6 | |
| 9 | 7.92 d (9.6) | 118.6 |
| 10 | 7.81 d (9.6) | 122.9 |
| 10a | 125.1 | |
| 11 | 3.29 m | 31.4 |
| 12 | 3.14 m | 61.9 |
| OCH2O | 6.19 s | 100.9 |
| 7-OCH3 | 4.00 s | 56.3 |
| 8-OCH3 | 3.98 s | 61.2 |
| N–CH3 | 2.81 s | 46.9 |
|
2.09 s | 19.5 |
|
169.7 | |
Assignments were based on 1H–1H COSY, HMQC, HMBC, and NOESY experiments; chemical shifts (δ) are given in ppm.
Recorded in CDCl3.