The NMR data of compounds 1–2.
No. | Compound 1 | Compound 2 | ||
---|---|---|---|---|
δ H a J (Hz) | δ C b | δ H a J (Hz) | δ C b | |
1 | 5.33 d, 3.2 | 6.29 s | ||
2 | 3.51 d, 4.2 | 68.9 | 4.01 br. s | 63.4 |
3 | 3.34 m | 53.8 | 3.68 br. s | 70.9 |
4 | ||||
5 | 3.22 m | 61.0 | 3.72 d, 3.5 | 74.7 |
6 | 2.40 dd, 10.9, 4.8 | 36.0 | 2.31 d, 11.9 | 31.2 |
1.47 d, 10.9 | 2.24 m | |||
7 | 57.7 | 57.0 | ||
8 | 131.9 | 129.7 | ||
9 | 6.75 d, 7.6 | 119.6 | 6.66 d, 7.7 | 118.9 |
10 | 6.56 t, 7.6 | 118.2 | 6.53 t, 7.7 | 118.6 |
11 | 6.84 d, 7.6 | 114.3 | 6.77 d, 7.7 | 112.7 |
12 | 143.0 | 143.4 | ||
13 | 141.7 | 141.2 | ||
14 | 2.46 dd, 13.8, 4.9 | 22.1 | 2.56 dd, 13.2, 4.1 | 21.8 |
1.36 dd, 13.8, 9.9 | 1.89 t, 11.8 | |||
15 | 3.35 m | 30.0 | 3.49 d, 4.1 | 29.0 |
16 | 59.9 | 60.5 | ||
17 | 4.08 d, 6.6 | 73.2 | 3.93 s | 72.7 |
18 | 1.52 d, 6.6, 3H | 12.5 | 1.57 d, 6.2, 3H | 12.3 |
19 | 5.14 q, 6.6 | 114.2 | 5.33 q, 6.2 | 117.8 |
20 | 139.0 | 131.3 | ||
21 | 3.28 m | 54.8 | 4.22 d, 15.0 | 69.7 |
3.25 m | 3.65 m | |||
22 | 172.7 | 170.7 | ||
1′ | 4.67 d, 7.3 | 101.7 | 4.73 d, 7.3 | 100.6 |
2′ | 3.23 m | 73.4 | 3.23 m | 73.4 |
3′ | 3.29 m | 77.1 | 3.32 m | 76.8 |
4′ | 3.14 m | 69.9 | 3.15 m | 70.0 |
5′ | 3.26 m | 76.0 | 3.30 m | 76.0 |
6′ | 3.72 m | 60.9 | 3.71 m | 60.9 |
3.46 m | 3.45 m | |||
–OCH3 | 3.53 s, 3H | 50.9 | 3.60 s, 3H | 51.7 |
Recorded at 500 MHz in DMSO-d6.
Recorded at 125 MHz in DMSO-d6.