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. 2021 Aug 16;11(44):27689–27700. doi: 10.1039/d1ra04979h

Summary of the leaching systems for metals recovery from spent LCO batteries.

Spent materials Leaching reagents Reaction conditions Leaching efficiency (%) Ref.
Temp. (°C) S/L ratio (g L−1) Time (min)
LCO 2 M H2SO4 + 5 vol% H2O2 75 100 30 Li = 94, Co = 93 23
2 M H2SO4 + 8 vol% H2O2 70 20 60 Li = 99, Co = 99 24
2 M H2SO4 + 5 vol% H2O2 80 50 60 Li = 99, Co = 99 25
1 M H2SO4 +0.075 M NaHSO3 95 20 240 Li = 97, Co = 92 26
0.23 M H2C2O4 + 3.6 vol% H2O2 100 15 180 Li = 91, Co = 97 27
2 M citric acid + 0.6 g g−1 H2O2 90 15 30 Li = 100, Co = 91 28
0.1 M citric acid + 0.02 M ascorbic acid 80 10 360 Li = 100, Co = 80 29
57.8 vol% lemon juice + 8.07 vol% H2O2 60 9.8 45 Li = 100, Co = 96 30
2 M l-tartaric acid + 4 vol% H2O2 70 17 30 Li = 99, Co = 96 31
1.5 M succinic acid + 4 vol% H2O2 70 15 40 Li = 96, Co = 99.5 32