Summary of the leaching systems for metals recovery from spent LCO batteries.
Spent materials | Leaching reagents | Reaction conditions | Leaching efficiency (%) | Ref. | ||
---|---|---|---|---|---|---|
Temp. (°C) | S/L ratio (g L−1) | Time (min) | ||||
LCO | 2 M H2SO4 + 5 vol% H2O2 | 75 | 100 | 30 | Li = 94, Co = 93 | 23 |
2 M H2SO4 + 8 vol% H2O2 | 70 | 20 | 60 | Li = 99, Co = 99 | 24 | |
2 M H2SO4 + 5 vol% H2O2 | 80 | 50 | 60 | Li = 99, Co = 99 | 25 | |
1 M H2SO4 +0.075 M NaHSO3 | 95 | 20 | 240 | Li = 97, Co = 92 | 26 | |
0.23 M H2C2O4 + 3.6 vol% H2O2 | 100 | 15 | 180 | Li = 91, Co = 97 | 27 | |
2 M citric acid + 0.6 g g−1 H2O2 | 90 | 15 | 30 | Li = 100, Co = 91 | 28 | |
0.1 M citric acid + 0.02 M ascorbic acid | 80 | 10 | 360 | Li = 100, Co = 80 | 29 | |
57.8 vol% lemon juice + 8.07 vol% H2O2 | 60 | 9.8 | 45 | Li = 100, Co = 96 | 30 | |
2 M l-tartaric acid + 4 vol% H2O2 | 70 | 17 | 30 | Li = 99, Co = 96 | 31 | |
1.5 M succinic acid + 4 vol% H2O2 | 70 | 15 | 40 | Li = 96, Co = 99.5 | 32 |