Tabulated absorption wavelengths (nm) and major contribution with oscillator strength for the studied dyes in their acetone, ethanol, gas and water phases.
Excitation | Wavelength (nm) | Energy (eV) | Oscillator strength | Major contribution (%) | Assignment |
---|---|---|---|---|---|
Dye A | |||||
Acetone | |||||
S0 → S1 | 505.81 | 2.4512 | 0.355 | H → L (96.24%) | π → π* |
S0 → S2 | 489.65 | 2.5321 | 0.054 | H−1 → L (57.73%) | n → π* |
S0 → S3 | 400.52 | 3.0956 | 0.079 | H → L+1 (72.17%) | n → π* |
Ethanol | |||||
S0 → S1 | 512.85 | 2.4175 | 0.368 | H → L (97.47%) | π → π* |
S0 → S2 | 491.97 | 2.5202 | 0.040 | H−1 → L (59.78%) | n → π* |
S0 → S3 | 410.24 | 3.0222 | 0.040 | H → L+1 (87.51%) | n → π* |
Gas | |||||
S0 → S1 | 495.50 | 2.5022 | 0.018 | H−1 → L (70.16%) | π → π* |
S0 → S2 | 483.66 | 2.5635 | 0.322 | H → L (79.89%) | n → π* |
S0 → S3 | 385.25 | 3.2183 | 0.255 | H−2 → L (58.31%) | n → π* |
Water | |||||
S0 → S1 | 515.17 | 2.4067 | 0.358 | H → L (97.53%) | π → π* |
S0 → S2 | 492.24 | 2.9931 | 0.040 | H−1 → L (58.25%) | n → π* |
S0 → S3 | 414.23 | 2.9931 | 0.040 | H → L+1 (89.27%) | n → π* |
Dye B | |||||
Acetone | |||||
S0 → S1 | 487.31 | 2.5443 | 0.0598 | H → L (96.24%) | π → π* |
S0 → S4 | 314.97 | 3.9364 | 0.3518 | H−1 → L (58.81%) | n → π* |
S0 → S5 | 292.48 | 4.2391 | 0.4152 | H → L+2 (65.99%) | n → π* |
Ethanol | |||||
S0 → S2 | 371.59 | 3.3412 | 0.8708 | H → L (69.83%) | |
S0 → S4 | 315.84 | 3.9255 | 0.3740 | H−1 → L (62.76%) | |
S0 → S5 | 292.01 | 4.2459 | 0.3993 | H → L (67.87%) | |
Gas | |||||
S0 → S2 | 349.76 | 3.5449 | 0.8057 | H → L (69.49%) | n → π* |
S0 → S4 | 311.85 | 3.9757 | 0.0836 | H−2 → L (30.31%) | n → π* |
S0 → S5 | 294.23 | 4.2139 | 0.6149 | H → L+2 (38.79%) | π → π* |
Water | |||||
S0 → S2 | 371.74 | 3.3353 | 0.8537 | H → L (69.78) | |
S0 → S3 | 314.86 | 3.9377 | 0.0022 | H−1 → L (63.91) | |
S0 → S5 | 291.28 | 4.2565 | 0.3891 | H → L+2 (67.87) | |
Dye C | |||||
Acetone | |||||
S0 → S1 | 505.81 | 2.4512 | 0.3558 | H → L (96.24%) | π → π* |
S0 → S2 | 489.65 | 2.5321 | 0.0543 | H−1 → L (57.73%) | n → π* |
S0 → S3 | 400.52 | 3.0956 | 0.0791 | H → L+1 (72.17%) | n → π* |
Ethanol | |||||
S0 → S1 | 512.85 | 2.4175 | 0.3686 | H → L (97.47%) | π → π* |
S0 → S2 | 491.97 | 2.5202 | 0.0430 | H−1 → L (59.78%) | n → π* |
S0 → S3 | 410.24 | 3.0222 | 0.0403 | H → L+1 (87.51%) | n → π* |
Gas | |||||
S0 → S1 | 495.50 | 2.5022 | 0.0187 | H−1 → L (70.06%) | π → π* |
S0 → S2 | 483.66 | 2.5635 | 0.3228 | H → L (79.89%) | n → π* |
S0 → S3 | 385.25 | 3.2183 | 0.2550 | H−2 → L (58.31%) | n → π* |
Water | |||||
S0 → S1 | 515.17 | 2.4067 | 0.3587 | H → L (97.53%) | π → π* |
S0 → S2 | 492.24 | 2.5188 | 0.0407 | H → L (58.25%) | n → π* |
S0 → S3 | 414.23 | 2.9931 | 0.0409 | H → L+1 (89.27%) | n → π* |
Dye D | |||||
Acetone | |||||
S0 → S1 | 542.60 | 2.2850 | 0.1455 | H−1 → L (59.79%) | π → π* |
S0 → S2 | 450.68 | 2.7510 | 0.4527 | H → L (65.39%) | n → π* |
S0 → S3 | 353.24 | 3.5099 | 0.5240 | H−2 → L (83.44%) | n → π* |
Ethanol | |||||
S0 → S1 | 542.49 | 2.2855 | 0.1463 | H−1 → L (59.88%) | π → π* |
S0 → S2 | 451.08 | 2.7486 | 0.4517 | H → L (65.55%) | n → π* |
S0 → S3 | 353.39 | 3.5084 | 0.5260 | H−3 → L (83.67%) | n → π* |
Gas | |||||
S0 → S1 | 552.60 | 2.2437 | 0.0786 | H → L (46.63%) | π → π* |
S0 → S2 | 417.84 | 2.9673 | 0.4323 | H−1 → L (48.92%) | n → π* |
S0 → S3 | 368.22 | 3.3672 | 0.0003 | H−3 → L (83.67%) | n → π* |
Water | |||||
S0 → S1 | 541.76 | 2.2886 | 0.1450 | H−1 → L (60.48%) | π → π* |
S0 → S2 | 451.84 | 2.7440 | 0.4426 | H → L (66.30%) | n → π* |
S0 → S3 | 353.63 | 3.5060 | 0.5259 | H−3 → L (84.02%) | n → π* |