Table 2. 13C NMR Data (200 MHz) of Compounds 1–4 in CDCl3.
| δC, type |
||||
|---|---|---|---|---|
| atom# | 1 | 2 | 3 | 4 |
| 1 | 40.1, CH2 | 40.1, CH2 | 41.0, CH2 | 41.1, CH2 |
| 2 | 70.3, CH | 69.9, CH | 71.2, CH | 70.7, CH |
| 3 | 79.0, CH | 78.9, CH | 80.1, CH | 80.0, CH |
| 4 | 39.3, C | 39.2, C | 39.3, C | 39.3, C |
| 5 | 49.3, CH | 49.3, CH | 49.9, CH | 50.0, CH |
| 6 | 36.2, CH2 | 36.2, CH2 | 17.9, CH2 | 17.9, CH2 |
| 7 | 197.8, C | 197.8, C | 25.8, CH2 | 25.9, CH2 |
| 8 | 139.2, C | 139.1, C | 134.8, C | 134.7, C |
| 9 | 163.1, C | 163.0, C | 134.2, C | 134.2, C |
| 10 | 40.5, C | 40.5, C | 37.8, C | 37.9, C |
| 11 | 23.8, CH2 | 23.8, CH2 | 33.8, CH2 | 34.0, CH2 |
| 12 | 29.9, CH2 | 29.9, CH2 | 72.8, CH2 | 72.8, CH2 |
| 13 | 44.9, C | 44.9, C | 49.0, C | 49.0, C |
| 14 | 47.8, C | 47.8, C | 52.2, C | 52.2, C |
| 15 | 31.8, CH2 | 31.8, CH2 | 31.2, CH2 | 31.1, CH2 |
| 16 | 28.6, CH2 | 28.6, CH2 | 25.1, CH2 | 25.2, CH2 |
| 17 | 48.9, CH | 48.9, CH | 50.5, CH | 50.6, CH |
| 18 | 15.8, CH3 | 15.7, CH3 | 9.9, CH3 | 9.8, CH3 |
| 19 | 19.4, CH3 | 19.4, CH3 | 20.0, CH3 | 20.0, CH3 |
| 20 | 35.9, CH | 35.9, CH | 33.8, CH | 33.8, CH |
| 21 | 18.5, CH3 | 18.5, CH3 | 21.2, CH3 | 21.2, CH3 |
| 22 | 30.1, CH2 | 30.0, CH2 | 29.1, CH2 | 29.1, CH2 |
| 23 | 32.6, CH2 | 32.5, CH2 | 33.7, CH2 | 33.6, CH2 |
| 24 | 214.9, C | 214.8, C | 215.2, C | 215.1, C |
| 25 | 76.2, C | 76.2, C | 76.3, C | 76.2, C |
| 26 | 26.5, CH3 | 26.6, CH3 | 26.5, CH3 | 26.5, CH3 |
| 27 | 26.5, CH3 | 26.5, CH3 | 26.5, CH3 | 26.5, CH3 |
| 28 | 25.0, CH3 | 25.0, CH3 | 24.2, CH3 | 24.1, CH3 |
| 29 | 17.3, CH3 | 17.2, CH3 | 17.4, CH3 | 17.4, CH3 |
| 30 | 27.6, CH3 | 27.6, CH3 | 28.2, CH3 | 28.2, CH3 |
| 1′ | 170.8, C | 171.2, C | 171.5, C | 171.4, C |
| 2′ | 44.9, CH2 | 44.8, CH2 | 44.7, CH2 | 44.9, CH2 |
| 3′ | 69.6, C | 69.5, C | 69.7, C | 69.5, C |
| 4′ | 27.1, CH3 | 27.3, CH3 | 27.2, CH3 | 26.5, CH3 |
| 5′ | 44.8, CH2 | 44.7, CH2 | 45.0, CH2 | 44.7, CH2 |
| 6′ | 173.7, C | 172.1, C | 173.5, C | 172.1, C |
| 7′ | 51.7, CH3 | 51.7, CH3 | ||
| 3-OAc | 171.4, C | 170.6, C | 171.1, C | 170.8, C |
| 20.9, CH3 | 20.9, CH3 | 21.0, CH3 | 21.0, CH3 | |