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. 2021 Sep 10;11(48):30222–30228. doi: 10.1039/d1ra05328k

Synthesis of cyclic carbonates catalyzed by Py-C12 in the presence of g-C3N4a.

Entry Epoxides Product Yieldb (%)
1 graphic file with name d1ra05328k-u1.jpg graphic file with name d1ra05328k-u2.jpg 95.2
2 graphic file with name d1ra05328k-u3.jpg graphic file with name d1ra05328k-u4.jpg 95.8
3 graphic file with name d1ra05328k-u5.jpg graphic file with name d1ra05328k-u6.jpg 94.9
4 graphic file with name d1ra05328k-u7.jpg graphic file with name d1ra05328k-u8.jpg 94.8
5c graphic file with name d1ra05328k-u9.jpg graphic file with name d1ra05328k-u10.jpg 96.5
6c graphic file with name d1ra05328k-u11.jpg graphic file with name d1ra05328k-u12.jpg 93.5
7d graphic file with name d1ra05328k-u13.jpg graphic file with name d1ra05328k-u14.jpg 94.6
a

Reaction conditions: epoxides (10 mmol), g-C3N4 (15 mg), Py-C12 (23.8 mg), CO2 (0.1 MPa), 80 °C, 16 h.

b

Detected by 1H-NMR.

c

32 h.

d

48 h.