Conditions of free-radical polymerizations and dispersion polymerizations of 2-(dimethylamino)ethyl methacrylate and ethylene dimethacrylate and properties of final poly[2-(dimethylamino)ethyl methacrylate-co-ethylene dimethacrylate] nanogels.
Sample | EDMA (wt%) | Solvent (wt%) | KPS (wt%) | SDS (wt%) | PVA (wt%) | PVP (wt%) | D n (nm) | D w (nm) | Đ | Yield (%) |
---|---|---|---|---|---|---|---|---|---|---|
PDMAEMA-EDMA01 | 1 | Water (100) | 0.15 | — | — | — | Aggregation | 6.4 | ||
PDMAEMA-EDMA02 | 2 | Water (100) | 0.15 | — | — | — | Aggregation | 6.5 | ||
PDMAEMA-EDMA03 | 3 | Water (100) | 0.15 | — | — | — | 360 | 401 | 1.11 | 3.9 |
PDMAEMA-EDMA04 | 4 | Water (100) | 0.15 | — | — | — | 359 | 420 | 1.17 | 1.5 |
PDMAEMA-EDMA05 | 5 | Water (100) | 0.15 | — | — | — | 359 | 395 | 1.10 | 2.2 |
PDMAEMA-EDMA06 | 10 | Water (100) | 0.15 | — | — | — | 366 | 426 | 1.17 | 33.6 |
PDMAEMA-EDMA07 | 20 | Water (100) | 0.15 | — | — | — | 292 | 332 | 1.14 | 41.2 |
PDMAEMA-EDMA08 | 10 | Water (100) | 0.2 | — | — | — | Aggregation | 42.7 | ||
PDMAEMA-EDMA09 | 20 | Water (100) | 0.2 | — | — | — | Aggregation | 38.5 | ||
PDMAEMA-EDMA10 | 10 | Water (100) | 0.2 | 0.15 | — | — | Aggregation | 49.2 | ||
PDMAEMA-EDMA11 | 20 | Water (100) | 0.2 | 0.15 | — | — | Aggregation | 62.1 | ||
PDMAEMA-EDMA12 | 20 | Water/EtOH (90/10) | 0.2 | 0.15 | — | — | Aggregation | 43.8 | ||
PDMAEMA-EDMA13 | 20 | Water/EtOH (80/20) | 0.2 | 0.15 | — | — | Aggregation | 47.0 | ||
PDMAEMA-EDMA14 | 20 | Water/EtOH (90/10) | 0.2 | — | — | — | Aggregation | 35.1 | ||
PDMAEMA-EDMA15 | 20 | Water/EtOH (80/20) | 0.2 | — | — | — | Aggregation | 50.1 | ||
PDMAEMA-EDMA16 | 20 | Water/EtOH (80/20) | 0.2 | — | 1.0 | — | Aggregation | 29.6 | ||
PDMAEMA-EDMA17 | 20 | Water/EtOH (80/20) | 0.2 | — | 0.5 | — | Aggregation | 30.3 | ||
PDMAEMA-EDMA18 | 20 | Water/EtOH (70/30) | 0.2 | — | 0.5 | — | Aggregation | 9.7 | ||
PDMAEMA-EDMA19 | 20 | Water/MeOH (90/10) | 0.2 | — | 0.5 | — | Aggregation | 8.3 | ||
PDMAEMA-EDMA20 | 20 | Water/MeOH (80/20) | 0.2 | — | 0.5 | — | 256 | 292 | 1.14 | 38.7 |
PDMAEMA-EDMA21 | 20 | Water/MeOH (75/25) | 0.2 | — | 0.5 | — | Aggregation | 28.3 | ||
PDMAEMA-EDMA22 | 20 | Water/MeOH (80/20) | 0.25 | — | 0.5 | — | 168 | 180 | 1.07 | 30.2 |
PDMAEMA-EDMA23 | 20 | Water/MeOH (80/20) | 0.3 | — | 0.5 | — | 201 | 216 | 1.08 | 22.6 |
PDMAEMA-EDMA24 | 20 (38) | Water/MetCel (80/20) | 0.2 | 0.15 | — | — | 169 | 199 | 1.18 | 52.2 |
PDMAEMA-EDMA25 | 20 (39) | Water/MetCel (80/20) | 0.2 | — | 0.5 | — | 167 | 193 | 1.16 | 51.0 |