Isolated yields of trioxolane adducts obtained under either conventional reaction condition A (in CCl4, 0 °C) or low temperature condition B (in hexane, −78 °C).
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Product (3a–f) | A: CCl4, 0 °C | B: hexane, −78 °C | |
3a |
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48–91% | 91% |
3b |
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28%a | 50% |
3c |
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23% | 77% |
3d |
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5% | 85% |
3e |
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18% | 94% |
3f |
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0% | 81% |
Calculated yield based on 1H NMR.