1H NMR (600 MHz) and 13C NMR (150 MHz) data for compounds 6a/6b in CD3OD.
Position | 6a | 6b | ||
---|---|---|---|---|
δ C, mult. | δ H, mult. (J in Hz) | δ C, mult. | δ H, mult. (J in Hz) | |
1 | 183.3, C | 182.6, C | ||
2 | 45.7, C | 44.7, C | ||
3 | 81.4, CH | 3.93, brs | 83.5, CH | 3.95, brs |
4 | 87.7, C | 86.0, C | ||
5 | 138.2, CH | 5.89, d (14.5) | 134.7, CH | 6.01, dd (14.8, 2.6) |
6 | 129.1, CH | 6.27, m | 129.7, CH | 6.27, m |
7 | 130.7, CH | 6.27, m | 131.1, CH | 6.27, m |
8 | 137.2, CH | 5.80, dd (14.6, 6.4) | 136.7, CH | 5.77, dd (14.5, 6.4) |
9 | 71.0, CH | 4.43, q (6.4) | 71.1, CH | 4.43, q (6.4) |
10 | 34.3, CH2 | 2.94, dd (15.6, 6.2) | 34.3, CH2 | 2.94, dd (15.6, 6.2) |
2.91, dd (15.6, 7.2) | 2.91, dd (15.6, 7.2) | |||
11 | 151.7, C | 151.7, C | ||
12 | 124.0, CH | 6.90, s | 124.0, CH | 6.90, s |
13 | 152.6, CH | 8.09, s | 152.6, CH | 8.08, s |
14 | 20.4, CH3 | 1.19, s | 19.7, CH3 | 1.04, s |
15 | 26.2, CH3 | 1.22, s | 25.3, CH3 | 1.21, s |
16 | 22.0, CH3 | 1.43, s | 27.4, CH3 | 1.49, s |