. 2021 Nov 15;11(58):36663–36669. doi: 10.1039/d1ra06885g

Electrochemical data for chiral photocatalysts 1c–g in DCM. Cyclic voltammetry of photocatalysts (V vs. Ag⁺/Ag), in dichloromethane (with 0.1 M Bu₄NPF₆ as electrolyte) on glassy carbon electrode. Concentrations are about 2 × 10⁻³ mmol mL⁻¹.

PCat	E _1/2 (1/1˙⁻, V vs. Ag⁺/Ag)	E _1/2 (1˙⁻/1²⁻, V vs. Ag⁺/Ag)	E _1/2 ^a (1/1˙⁻, V vs. Ag⁺/Ag)	E _1/2 ^a (1˙⁻/1²⁻, V vs.* Ag⁺/Ag)
1a	−1.96		+1.10
1b	−1.10	−1.48	+1.70	+1.32
1c	−1.09	−1.53	+1.71	+1.27
1d	−1.70		+1.17
1e	−1.72^b	−2.04		+1.22

Calculated using the relationship E°(Pcat 1*/1˙⁻) = E_1/2 (Pcat 1/1˙⁻) + E_0,0 (Pcat 1*/1) and E_0,0 values were estimated spectroscopically from the position of the long wavelength tail of the absorption spectrum (Table S1 in the ESI).

No oxidation peak.

Electrochemical data for chiral photocatalysts 1c–g in DCM. Cyclic voltammetry of photocatalysts (V vs. Ag+/Ag), in dichloromethane (with 0.1 M Bu4NPF6 as electrolyte) on glassy carbon electrode. Concentrations are about 2 × 10−3 mmol mL−1.

Electrochemical data for chiral photocatalysts 1c–g in DCM. Cyclic voltammetry of photocatalysts (V vs. Ag⁺/Ag), in dichloromethane (with 0.1 M Bu₄NPF₆ as electrolyte) on glassy carbon electrode. Concentrations are about 2 × 10⁻³ mmol mL⁻¹.