Kinetic parameters of prepared transition metal complexes.

Compound	Step	n order	T (K)	A (S-1)	E (kJ mol−1)	ΔH (kJ mol−1)	ΔS (kJ mol−1)	ΔG (kJ mol−1)
Co(ii) complex	1St	0.50	348	5.72 × 104	36.46	33.56	−0.11	73.32
	2nd	0.33	417	9.27 × 106	60.28	56.82	−0.12	107.69
	3rd	1.00	551	4.34 × 103	49.83	45.25	−0.18	148.89
	4th	1.00	751	1.63 × 108	135.02	128.78	−0.10	206.20
Ni(ii) complex	1St	0.33	352	5.86 × 102	30.90	27.97	−0.22	105.46
	2nd	0.33	403	1.8 × 107	59.60	56.25	−0.11	103.06
	3rd	1.00	473	1.39 × 106	63.92	59.99	−0.13	125
	4th	1.00	561	3.94 × 106	71.38	66.72	−0.11	130.5
	5th	0.66	719	8.68 × 102	56.55	50.58	−0.20	196.77
Cu(ii) complex	1St	1	338	1.34 × 108	55.17	52.36	−0.09	85.51
	2nd	0.50	462	1.37 × 104	45.23	41.39	−0.17	123.17
	3rd	1.00	548	5.84 × 10	30.90	26.35	−0.22	148.99
Cd(ii) complex	1St	1.00	339	8.62 × 105	42.43	39.61	−0.14	87.123
	2nd	0.33	448	2.65 × 106	66.16	62.44	−0.13	122.04
	3rd	0	523	5.09 × 108	94.56	90.22	−0.09	137.64
	4th	0.50	561	2.26 × 106	77.69	73.02	−0.13	149.45
	5th	0.50	666	6.92 × 106	89.28	83.75	−0.12	169.25