Scope of styrene type methyl ethersa.
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Reaction conditions: 1 (0.3 mmol), 2 (0.6 mmol), HSiEt3 (0.9 mmol) and K3PO4 (0.45 mmol) were reacted in toluene (1.5 mL) at 110 °C for 24 h under nitrogen atmosphere. Yields were obtained after purification through column chromatography on silica gel.
React for 48 h.
20 mol% Ni(acac)2, 20 mol% IMes·HCl, 40 mol% Zn, 1 (0.3 mmol), 2 (1.2 mmol), HSiEt3 (1.8 mmol) and K3PO4 (0.9 mmol) were reacted in toluene (3 mL) at 110 °C for 24 h under nitrogen atmosphere.