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. 2021 Dec 7;11(62):39051–39057. doi: 10.1039/d1ra07232c

Additive linear changes of 13C chemical shifts of 2-alkanones versus H/D substitution site (in ppb). Positive values denote upfield shift.

C1 C2 C3 C4 C5
1Δa 3Δb 2Δa 2Δb 1Δb 3Δa 2Δb 4Δa 3Δb 5Δa
MtBK 237.8 6.6 13.5
MiPK 246.5 4.0 −44.7 −85.5 437.3 <2 99.3 12.9
MEK 245.5 5.0 −49.7 −84.5 334.9 <2 74.5 10.4
MPK 247.3 2.0 −51.7 −84.5 357.8 <2 54.7 10.4 24.8 0
MBK 247.5 3.5 −51.7 −84.5 350.8 <2 54.7 10.4 21.9 0
MHK 247.5 3.0 −51.7 −84.5 352.8 <2 54.7 10.9 22.9 0
Acetone 246.5 −55.2
MPhK 240.5 −41.7