Magnetic nano-catalyst catalyzed synthesis of 1-substituted tetrazole containing scaffolds via one pot MCR between amine with tri-ethyl orthoformate and azides.
Entry | Catalyst | Solvent | Catalyst loading | Temperature (°C) | Time (h) | Yield (%) | Ref. |
---|---|---|---|---|---|---|---|
1 | Fe3O4@silica sulfonic acid | — | 0.02 g | 100 | 50 | 97 | 53 |
2 | Chitosan supported magnetic ionic liquid nanoparticles (CSMIL) | — | 2.5 mol% | 70 | 1 | 92 | 54 |
3 | Fe3O4@Quinol@Cu | — | 0.01 g | 100 | 40 | 92 | 55 |
4 | Fe3O4@Phen@Mn | — | 50 mg | 100 | 40 | 92 | 56 |
5 | Fe3O4@WO3-EAE-SO3H(iii) | H2O | 0.01 g | 60 | 30 | 95 | 57 |
6 | Fe3O4/HT-NH2-CuII | H2O | 0.005 g | 90 | 1 | 94 | 58 |
7 | Fe3O4@HT@AEPH2-CoII | H2O | 0.005 g | 90 | 60 | 95 | 59 |
8 | Fe3O4/HT-GLYMO-TA | H2O | 0.02 g | 90 | 45 | 95 | 50 |