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. Author manuscript; available in PMC: 2022 Apr 28.
Published in final edited form as: Biochemistry. 2022 Apr 5;61(8):689–702. doi: 10.1021/acs.biochem.1c00774

Scheme 1.

Scheme 1.

The Bes biosynthetic pathway involving iron(II)- and 2-oxoglutarate-dependent halogenase, BesD, and desaturase/lyase, BesC. The lower path indicates that BesC also analogously fragments L-lysine.