Kinetic parameters for photocatalysis (SF/TiO2 and TiO2) of pesticides in water under natural sunlight.
Pesticide | SF/TiO2 | TiO2 | ||||
---|---|---|---|---|---|---|
R 2 | k × 102 (min−1) | t ½ a (min) | R 2 | k × 102 (min−1) | t ½ a (min) | |
Boscalid | 0.859 | 0.867 | 79.7 | 0.908 | 1.904 | 36.5 |
Pyraclostrobin | 0.897 | 1.836 | 36.7 | 0.827 | 3.217 | 21.5 |
Hexythiazox | 0.731 | 2.506 | 27.6 | 0.759 | 5.287 | 13.1 |
Trifloxystrobin | 0.841 | 2.398 | 28.9 | 0.782 | 4.615 | 15.0 |
Referred to t30 W (calculated according eqn (1)).