The experimentally determined and laboratory prepared (gravimetric) scalemic ratio of (R)-(+)-α-methylbenzylamine and (S)-(−)-α-methylbenzylamine. The C(H)NH2 peak was chosen to measure ee.
(R) Enantiomer | (S) Enantiomer | ||||
---|---|---|---|---|---|
Gravimetric (ee) | Experimental (NMR) (ee) | Integral (abs) | Gravimetric | Experimental (NMR) (ee) | Integral (abs) |
50.00 | 50.1 | 1 339 481 586 | 50.00 | 49.9 | 1 335 540 873 |
70.00 | 69.1 | 5 834 674 654 | 30.00 | 30.9 | 2 607 902 814 |
75.00 | 74.9 | 3 757 999 390 | 25.00 | 25.1 | 1 257 315 684 |
87.00 | 88.7 | 5 621 687 032 | 13.00 | 11.3 | 717 636 699 |
95.00 | 94.8 | 8 656 606 700 | 5.00 | 5.2 | 472 201 958 |