Activation parameters for the spin probe TEMPO in the confined n-PrOH/MCM-41 system.
| Regime/region | ΔT K | log τ∞ (—) | E kJ mol−1 | r (—) |
|---|---|---|---|---|
| Slow-I | 100–120 | −6.19 ± 0.01 | 1.98 ± 0.07 | 0.999 |
| Slow-II | 140–250 | −10.31 ± 0.08 | 586.82 ± 15.18 | 0.996 |
| Slow-III | 260–310 | −9.15 ± 0.18 | 267.89 ± 51.3 | 0.984 |
| Fast-I | 150–200 | −9.02 ± 0.08 | 118,13 ± 14.45 | 0.972 |
| Fast-II | 210–250 | −12.37 ± 0.15 | 785.72 ± 34.87 | 0.996 |
| Fast-III | 260–330 | −11.31 ± 0.11 | 537.14 ± 30.88 | 0.990 |