Hydrosilylation of various alkenes and MDHM by Ptδ+/SBA-APTE-SA catalysta.
Entry | Substrate | Catalyst amount (mmol%) | Temperature (°C) | Time (min) | Conv. (%) | TON | TOF (h−1) |
---|---|---|---|---|---|---|---|
1 | Allyloxy polyethylene glycol (380) | 8.21 | 100 | 225 | 91.04 | 11 835 | 3156 |
2 | Acrylic polyethers (200) | 8.21 | 100 | 225 | 95.15 | 12 370 | 3299 |
3 | 1-Dodecene | 8.21 | 100 | 225 | 94.19 | 12 245 | 3265 |
4 | 1-Tetradecene | 8.21 | 100 | 225 | 90.54 | 11 770 | 3139 |
5 | Styrene | 8.21 | 100 | 225 | 97.35 | 12 656 | 3375 |
Reaction condition: MDHM = 0.02 mol; MDHM : alkene molar ratio, 1 : 1. nPt signifies the mole of Pt, nMDHM = 0.02 mol.