Polymerization conditions.
| Polymer | Polymerization method | Solvent | C m a (%) | S-Propranolol (mmol) | MAA (mmol) | Cross-linker (mmol) | IF | ||
|---|---|---|---|---|---|---|---|---|---|
| DSDMA | EDMA | BAC | |||||||
| M1 | Bulk | ACN | 46.9 | 0.015 | 0.12 | 0.6 | — | — | 7.2b |
| N1 | Bulk | ACN | 46.9 | — | 0.12 | 0.6 | — | — | — |
| M2 | Bulk | ACN | 46.9 | 0.015 | 0.12 | — | 0.6 | — | 6b |
| N2 | Bulk | ACN | 46.9 | — | 0.12 | — | 0.6 | — | — |
| M3 | Bulk | ACN | 46.9 | 0.015 | 0.12 | — | — | 0.6 | 1.5b |
| N3 | Bulk | ACN | 46.9 | — | 0.12 | — | — | 0.6 | — |
| M4 | High dilution | DMSO | 0.25 | 0.015 | 0.12 | 0.6 | — | — | 2.4c |
| N4 | High dilution | DMSO | 0.25 | — | 0.12 | 0.6 | — | — | — |
| M5 | High dilution | DMSO | 0.25 | 0.015 | 0.12 | — | 0.6 | — | 1.4c |
| N5 | High dilution | DMSO | 0.25 | — | 0.12 | — | 0.6 | — | — |
a
Abbreviation Cm, monomer concentration calculated as the mass ratio of functional monomer and cross-linker to the total mass of polymer formulation.
b
Imprinting factor determined for a polymer concentration of 0.08 g L−1.
c
Imprinting factor determined for a polymer concentration of 0.8 g L−1.