Emission parameter values of several meso-porphyrins and a selection of cobalt(ii) meso-metalloporphyrins.

Compound	λ exci a	Q(0,0)	Q(0,1)	ϕ f b	τ f c (in ns)	Solvent	Ref.
Free base meso-porphyrins
H2TMPP	424	656	719	0.082	7.16	CH2Cl2	This work
H2TClPP	418	651	714	0.089	7.42	CH2Cl2	This work
H2TPPd	—	654	712	0.11	—	CH2Cl2	43 and 44
H2TPPd	—	656	717	0.09	—	CH2Cl2	45
H2TPPd	—	653	722	0.12	9.6	DMF	46
Tetracoordinated cobalt( ii ) meso-metalloporhyrins
[CoII(TPBP)]e	552	653	719	0.032	—	CH2Cl2	7
[CoII(TMPP)]	414	655	719	0.035	6.02	CH2Cl2	This work
[CoII(TClPP)]	412	652	713	0.04	6.10	CH2Cl2	This work
Pentacoordinated and hexacoordinated cobalt( ii ) meso-porphyrins
[CoII(TPBP)(4,4′-bipy)2]e,f	550	652	718	0.036	—	CH2Cl2	7
[CoII(TMPP)(4-CNpy)]·CHCl3 (1)	437	652	717	0.054	1.97	CH2Cl2	This work
[CoII(TClPP)(4-CNpy)] (2)	439	653	714	0.06	1.997	CH2Cl2	This work

^a λ _exci = wavelength value of excitation.

^b ϕ _f = fluorescence quantum yields.

^c τ _f = fluorescent lifetime.

^dTPP = meso-tetraphenylporphyrinato.

^eTPBP = meso-{tetrakis-[4-(benzoyloxy)phenyl]porphyrinato}.

^f4,4′-bipy = 4,4′-bipyridine.