Thermal decomposition rate coefficient and Arrhenius activation energy of syn-CH3CHOO.
| k uni/s−1 | E a/kcal mol−1 | |
|---|---|---|
| This work | 146 ± 31a | 6.4 ± 0.2b |
| This work (assuming kw = 0) | 173 ± 31a | 7.1 ± 0.3b |
| Fang et al.14 | 166c | 8.5 ± 0.1b |
| Long et al.13 | 328c | 7.7 ± 0.2b |
| Nguyen et al.32 | 124c | 8.2 ± 0.4b |
| Yin et al.15 | 182c | 8.6 ± 0.2b |
a
At 298 K and 300 torr. The error bar is one standard deviation (see ESI).
b
The activation energy (including theoretical ones) is obtained from the slope of the linear fitting of log(k) against 1/T within 278–318 K; the error bar is one standard deviation of the fitting.
c
Theoretical result at 298 K at the high pressure limit.