Table 2.
Entry | Substrate | Product | Temp./°C | Time /h | Pressure /MPa | Conv./% | Sel./% |
---|---|---|---|---|---|---|---|
1b | 80 | 10 | 2 | 100 | >99 | ||
2 | 80 | 10 | 2 | 92.8 | >99 | ||
3 | 80 | 10 | 2 | 100 | >99 | ||
4 | 80 | 10 | 2 | 37.0 | >99 | ||
5 | 80 | 10 | 2 | 82.9 | >99 | ||
6 | 100 | 24 | 2 | 2.3 | >99 | ||
7 | 80 | 24 | 3 | 100 |
2.6 97.4 |
||
8 | 80 | 24 | 3 | 100 |
64.9 35.1 |
||
9b | 80 | 24 | 3 | 92.5 |
80 20 |
||
10 | 80 | 24 | 3 | 92.0 |
53.8 46.1 |
||
11 | 80 | 24 | 3 | 92.2 |
92.4 7.6 |
a Reaction conditions: substrate (0.2 mmol), THF (2 mL), AlOOH-U2 catalyst (50 mg), stirring speed (600 rpm); the substrate conversion and product selectivity were determined by GC with n-decane as internal standard
b n-Dodecane as internal standard.