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. 2022 Apr 28;13:2320. doi: 10.1038/s41467-022-29970-6

Table 2.

Scope of AlOOH-U2 for catalytic hydrogenation of alkenes and alkynes a.

Entry Substrate Product Temp./°C Time /h Pressure /MPa Conv./% Sel./%
1b graphic file with name 41467_2022_29970_Taba_HTML.gif graphic file with name 41467_2022_29970_Tabl_HTML.gif 80 10 2 100 >99
2 graphic file with name 41467_2022_29970_Tabb_HTML.gif graphic file with name 41467_2022_29970_Tabm_HTML.gif 80 10 2 92.8 >99
3 graphic file with name 41467_2022_29970_Tabc_HTML.gif graphic file with name 41467_2022_29970_Tabn_HTML.gif 80 10 2 100 >99
4 graphic file with name 41467_2022_29970_Tabd_HTML.gif graphic file with name 41467_2022_29970_Tabo_HTML.gif 80 10 2 37.0 >99
5 graphic file with name 41467_2022_29970_Tabe_HTML.gif graphic file with name 41467_2022_29970_Tabp_HTML.gif 80 10 2 82.9 >99
6 graphic file with name 41467_2022_29970_Tabf_HTML.gif graphic file with name 41467_2022_29970_Tabq_HTML.gif 100 24 2 2.3 >99
7 graphic file with name 41467_2022_29970_Tabg_HTML.gif

graphic file with name 41467_2022_29970_Tabr_HTML.gif

graphic file with name 41467_2022_29970_Tabs_HTML.gif

80 24 3 100

2.6

97.4

8 graphic file with name 41467_2022_29970_Tabh_HTML.gif

graphic file with name 41467_2022_29970_Tabt_HTML.gif

graphic file with name 41467_2022_29970_Tabu_HTML.gif

80 24 3 100

64.9

35.1

9b graphic file with name 41467_2022_29970_Tabi_HTML.gif

graphic file with name 41467_2022_29970_Tabv_HTML.gif

graphic file with name 41467_2022_29970_Tabw_HTML.gif

80 24 3 92.5

80

20

10 graphic file with name 41467_2022_29970_Tabj_HTML.gif

graphic file with name 41467_2022_29970_Tabx_HTML.gif

graphic file with name 41467_2022_29970_Taby_HTML.gif

80 24 3 92.0

53.8

46.1

11 graphic file with name 41467_2022_29970_Tabk_HTML.gif

graphic file with name 41467_2022_29970_Tabz_HTML.gif

graphic file with name 41467_2022_29970_Tabaa_HTML.gif

80 24 3 92.2

92.4

7.6

a Reaction conditions: substrate (0.2 mmol), THF (2 mL), AlOOH-U2 catalyst (50 mg), stirring speed (600 rpm); the substrate conversion and product selectivity were determined by GC with n-decane as internal standard

b n-Dodecane as internal standard.