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. 2020 Mar 27;10(21):12653–12670. doi: 10.1039/d0ra02254c

Main advantages and drawbacks of ultrathin membranes compared to those of traditional ones.

Advantages Drawbacks
➢ Attractive separation performance ➢ Specific devices for membrane preparation
➢ Higher productivity (high permeances) ➢ Hydrothermal stability issues on single-layered layers based on MOFs
➢ Low amount of selective membrane-material ➢ Challenging spatial distribution
➢ Defect-free structure ➢ Physical aging and plasticization in the polymer support and polymer-based layers
➢ Less membrane area needed for a given separation ➢ Limited preparation procedures at a large scale
➢ Controlled grain size and thickness ➢ Separation properties depending on precursors and ligands
➢ Controllable tuning of the membrane pore size ➢ Hydrothermal stability of ligand–metal bonds
➢ Stable mechanical properties (e.g., graphene-based membranes) for potential large-scale applications
➢ Atomically thin membranes
➢ Materials, fabrication, and energy cost savings