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. 2020 Apr 6;10(23):13855–13865. doi: 10.1039/d0ra00668h

BET surface area and surface atomic composition of the catalysts.

Sample Surface atomic concentration (%) X Mn/% X O/% X Pr/% BET (m2 g−1) Pore volume (cm3 g−1)
Mn O Pr Mn4+ Mn3+ Mn2+ Oα Oβ Pr4+ Pr3+
Hollow MnOx 39.47 60.53 49.01 37.02 13.97 83.05 16.95 136.70 0.24
Hollow MnOx@PrOx 12.62 54.19 33.19 58.27 33.24 8.49 29.7 70.3 60.4 39.6 195.31 0.36
Hollow MnOx–PrOx 34.58 50.19 15.23 51.1 37.3 11.6 57.36 42.64 66.4 33.6 185.39 0.31