Thermodynamic parameters ( (kJ mol−1), (kJ mol−1) and (J K−1 mol−1)) of all studied systemsa.
C CFH mmol kg−1 | |||||
---|---|---|---|---|---|
298.15 K | 303.15 K | 308.15 K | 313.15 K | 318.15 K | |
Water | |||||
0.0 | −30.73/7.49/128.19 | −31.67/0.21/105.15 | −32.72/−7.69/81.25 | −33.38/−16.10/55.19 | −33.95/−25.22/27.45 |
0.5 | −7.18/36.58/146.70 | −7.41/32.23/130.77 | −7.85/28.02/116.39 | −8.22/23.39/100.95 | −8.04/17.8/81.29 |
1.0 | −7.01/−14.18/−24.06 | −7.30/−18.93/−38.37 | −7.80/−24.24/−53.32 | −8.05/−29.27/−67.76 | −7.99/−34.27/−82.62 |
2.0 | −6.79/38.27/151.15 | −7.41/31.12/127.09 | −7.58/23.84/101.96 | −7.95/15.38/74.50 | −7.54/5.71/41.65 |
10 mmol kg −1 glucose | |||||
0.0 | −33.72/9.13/143.71 | −34.92/−10.71/79.84 | −36.13/−32.18/12.82 | −35.77/−54.21/−58.89 | −35.75/−77.53/−131.34 |
0.5 | −32.19/35.65/227.55 | −33.11/25.10/191.99 | −34.27/13.61/155.37 | −34.33/1.13/113.24 | −34.13/−11.90/69.87 |
1.0 | −31.52/−7.97/77.69 | −32.68/34.94/223.04 | −33.67/25.06/190.60 | −33.50/14.02/151.77 | −33.55/2.59/113.59 |
2.0 | −30.96/32.70/213.51 | −31.82/24.42/185.54 | −33.13/15.50/157.84 | −32.93/5.51/122.78 | −32.81/−4.84/87.91 |
10 mmol kg −1 fructose | |||||
0.0 | −32.57/64.67/326.15 | −34.06/48.96/273.84 | −35.14/31.34/215.73 | −35.17/−12.05/150.79 | −35.11/−8.25/84.42 |
0.5 | −31.28/48.67/268.15 | −32.21/35.71/224.04 | −33.47/21.57/178.61 | −33.31/6.14/125.97 | −33.35/−10.08/73.12 |
1.0 | −31.73/43.98/253.93 | −32.68/34.94/223.04 | −32.80/−21.62/36.30 | −32.75/−35.77/−9.62 | −32.87/−50.59/55.69 |
2.0 | −30.08/32.44/209.66 | −31.01/22.26/175.74 | −32.25/11.27/141.24 | −32.03/−0.82/99.69 | −32.09/−13.42/58.68 |
Relative standard uncertainty (ur) limits are = ±3%, = ±4% and = ±5%.