Methanol sensor efficiency under N2 base gas of the graphene-based materials, dPIn, and their compositesa.
| Material | Relative conductivity response | Response time (min) | Recovery time (min) | Reversibility |
|---|---|---|---|---|
| cm-G | (7.90 ± 3.58) × 10−3 | 11.67 ± 1.17 | — | Irrecoverable |
| cm-GO | 3.79 ± 0.3 | 16.15 ± 3.03 | 12.81 ± 3.43 | Fully recoverable |
| C-rGO | −0.10 ± 0.03 | 21.67 ± 4.50 | — | Partly recoverable |
| T-rGO | −0.48 ± 0.12 | 15.14 ± 0.31 | — | Partly recoverable |
| OIHM-GO | 1.53 ± 0.02 | 16.25 ± 3.78 | 1.29 ± 0.51 | Fully recoverable |
| dPIn38 | 57.83 ± 5.03 | 25.93 ± 1.44 | 18.88 ± 0.27 | Fully recoverable |
| In situ 10% v/v cm-G/dPIn | 0.71 ± 0.13 | 59.48 ± 7.26 | 4.52 ± 0.65 | Fully recoverable |
| In situ 10% v/v C-rGO/dPIn | 27.37 ± 2.22 | 54.84 ± 1.51 | 17.49 ± 1.01 | Fully recoverable |
| In situ 10% v/v T-rGO/dPIn | 20.03 ± 3.78 | 44.76 ± 2.31 | 19.83 ± 1.31 | Fully recoverable |
| In situ 10% v/v cm-GO/dPIn | 95.76 ± 3.77 | 54.03 ± 1.08 | 17.68 ± 0.82 | Fully recoverable |
| SM 10% v/v cm-GO/dPIn | 19.98 ± 1.63 | 78.23 ± 5.08 | 8.29 ± 1.78 | Fully recoverable |
| In situ 10% v/v OIHM-GO/dPIn | 81.89 ± 2.12 | 28.08 ± 1.93 | 19.91 ± 3.50 | Fully recoverable |
Remarks: (1) methanol concentration was constant at 11.36 ppm, 1.1 atm pressure, and 20 ± 3% RH. (2) Doping of PIn and composites was fixed at a 10 : 1 doping mole ratio of HClO4/indole. (3) In situ means the graphene-based materials/PIn composites were prepared by in situ polymerization. (4) SM means the graphene-based material/PIn composite was prepared by simple mixing.