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. 2020 Apr 17;10(26):15206–15220. doi: 10.1039/d0ra00158a

Methanol sensor efficiency under N2 base gas of the graphene-based materials, dPIn, and their compositesa.

Material Relative conductivity response Response time (min) Recovery time (min) Reversibility
cm-G (7.90 ± 3.58) × 10−3 11.67 ± 1.17 Irrecoverable
cm-GO 3.79 ± 0.3 16.15 ± 3.03 12.81 ± 3.43 Fully recoverable
C-rGO −0.10 ± 0.03 21.67 ± 4.50 Partly recoverable
T-rGO −0.48 ± 0.12 15.14 ± 0.31 Partly recoverable
OIHM-GO 1.53 ± 0.02 16.25 ± 3.78 1.29 ± 0.51 Fully recoverable
dPIn38 57.83 ± 5.03 25.93 ± 1.44 18.88 ± 0.27 Fully recoverable
In situ 10% v/v cm-G/dPIn 0.71 ± 0.13 59.48 ± 7.26 4.52 ± 0.65 Fully recoverable
In situ 10% v/v C-rGO/dPIn 27.37 ± 2.22 54.84 ± 1.51 17.49 ± 1.01 Fully recoverable
In situ 10% v/v T-rGO/dPIn 20.03 ± 3.78 44.76 ± 2.31 19.83 ± 1.31 Fully recoverable
In situ 10% v/v cm-GO/dPIn 95.76 ± 3.77 54.03 ± 1.08 17.68 ± 0.82 Fully recoverable
SM 10% v/v cm-GO/dPIn 19.98 ± 1.63 78.23 ± 5.08 8.29 ± 1.78 Fully recoverable
In situ 10% v/v OIHM-GO/dPIn 81.89 ± 2.12 28.08 ± 1.93 19.91 ± 3.50 Fully recoverable
a

Remarks: (1) methanol concentration was constant at 11.36 ppm, 1.1 atm pressure, and 20 ± 3% RH. (2) Doping of PIn and composites was fixed at a 10 : 1 doping mole ratio of HClO4/indole. (3) In situ means the graphene-based materials/PIn composites were prepared by in situ polymerization. (4) SM means the graphene-based material/PIn composite was prepared by simple mixing.