Selected applications of graphene QDs in modified sensors and biosensors.
Sensor | Electrochemical method | Analyte | Detection limit | Linear range | Sensitivity | Ref. |
---|---|---|---|---|---|---|
GQDs-Nafion/GCE | DPV | Dopamine | 0.45 nM | 0.005–100 μM | 0.0859 μA μM−1 | 138 |
GQD/GCE | SWV | Dopamine | — | 3–100 μM | — | 139 |
GQD-RuCl3 jCCE | Amperometry | l-Tyrosine | 0.23 μM | 1–937 μM | 90 nA mM−1 | 140 |
Fe3O4 MNPs-GQDs-GCE | DPV | l-Tyrosine | — | 0.09–230.0 μM | — | 141 |
rAuNPs/GQDs/GCE | SWV | Dopamine | 3.0 × 10−10 M | 1.0 × 10−9 to 1.0 × 10−7 M | 0.2245 μA μM−1 | 142 |
(GQDs-NHCH2CH2NH)/GCE | DPV | Dopamine | 0.115 μM | 1.0–150 μM | 1306 μA mM−1 cm−2 | 143 |
His-GQD-GMA/GCE | DPV | Dopamine | 2.9 × 10−10 M | 1.0 × 10−9 to 8.0 × 10−5 M | −0.5482 μA μM−1 | 144 |
CS/N,GQDs@SPCE | DPV | Dopamine | 0.145 μM | 1.0–200.0 μM | 418 μA mM cm−2 | 145 |
GCE/GQDs/Lac | CV | Epinephrine | 83 nM | 1.0–120.0 × 10−6 M | −2.9 mm M−1 cm−2 | 146 |
β-CD–GQD/GCE | DPV | l-Tyrosine | — | 0.1–1.5 μM | 863.8 μM mM−1 | 147 |
MIP/GQDs/2D-hBN/GCE | DPV | Serotonin | 2.0 × 10−13 M | 1.0 × 10−12 to 1.0 × 10−8 M | 29.819 μA nM−1 | 148 |
GQDs/GCE | DPV | Dopamine | 0.05 μM | 0.4–100.0 μM | −0.6145 μA μM−1 | 149 |
GQD/SPE | DPV | Dopamine | 0.05 μM | 0.1–1000.0 μM | 0.0745 μA μM−1 | 150 |
Tyrosine | 0.5 μM | 1.0–900.0 μM | 0.0495 μA μM−1 | |||
GQD-CS/CPE | Amperometry | Epinephrine | 0.3 nM | 0.36–380 μM | 41 296 μA μM−1 | 151 |
GCE/GQDs/AuNPs | SWSV | Norepinephrine | 0.15 μM | 0.5–7.5 μM | 4.2 × 10−7 μA L μmol−1 | 152 |
QD-TMSPED-AuNCs/GC | Amperometry | Dopamine | 5 nM | 5 nM to 2.1 μM | 0.007 to 0.01 μA nM−1 | 153 |
Epinephrine | 10 nM | 10 nM to 4.0 μM | 0.01 μA nM−1 | |||
GQDs/IL/CPE | DPV | Norepinephrine | 0.06 μM | 0.2–400.0 μM | 0.0951 μA μM−1 | 154 |