Figure 31.
Ultraviolet photodissociation (UVPD) tandem MS of a dermatan sulfate tetrasaccharide at 193 nm. (a) Product ion spectrum of the doubly deprotonated oligosaccharide (m/z 458). (b) The corresponding UVPD fragmentation pattern and structural assignment. (c) Donut plot depicting the distribution of photofragments based on summed abundances of fragment types. Reproduced with permission from ref (515). Copyright 2019 American Chemical Society.