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MicD-F and ArtGox tolerate diverse nonproteinogenic, non-α-amino acid monomers at the −1 site. (A) MicD-F and ArtGox reactions of substrates with non-α-amino acid monomers immediately C-terminal to the site of cyclization. (B) Yields of thiazoline 5(a-i) and thiazole (6(a-i)) products obtained. (C) Extracted ion chromatograms illustrating the products of MicD-F and ArtGox-catalyzed reactions.
