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. 2021 Sep 7;122(8):7562–7623. doi: 10.1021/acs.chemrev.1c00279

Figure 24.

Figure 24

UVPD of deuterated peptides can occur without scrambling. Deuterium content of various a ions are shown at conditions that prevent (top) or induce scrambling (bottom). The uptake measured is plotted in blue. Theoretical positions of the deuterium levels assuming no (green) or full (red) scrambling are indicated in dashed lines. Reproduced with permission from ref (258). Copyright 2018 American Chemical Society.