Fitting parameters for DP phototransformation under different reaction conditions by pseudo-first-order model.
| Reaction condition | K DP (min−1) | R 2 | t 1/2 (min) |
|---|---|---|---|
| No sand | (1.73 ± 0.02) × 10−3 | 0.999 | 400.7 |
| DS sand | (3.80 ± 0.05) × 10−3 | 0.999 | 182.4 |
| SS sand | (7.40 ± 0.04) × 10−3 | 0.986 | 93.7 |
| DS sand + IPA | (3.52 ± 0.07) × 10−3 | 0.998 | 196.9 |
| DS sand + BQ | (0.74 ± 0.07) × 10−3 | 0.961 | 936.7 |
| SS sand + IPA | (4.3 ± 0.3) × 10−3 | 0.984 | 161.2 |
| SS sand + BQ | (1.41 ± 0.06) × 10−3 | 0.993 | 491.6 |
| DS sand treated with H2O2 | (2.34 ± 0.08) × 10−3 | 0.994 | 296.2 |
| SS sand treated with H2O2 | (1.82 ± 0.08) × 10−3 | 0.989 | 380.9 |
| DS sand + N2 | (6.68 ± 0.02) × 10−3 | 0.997 | 103.7 |
| SS sand + N2 | (1.6 ± 0.2) × 10−2 | 0.927 | 43.3 |