Comparison of HCP-Pd with other catalysts for Suzuki–Miyaura reaction.
| Entry | Catalyst | React condition | Yield | TONa (×103) |
|---|---|---|---|---|
| 1 | KAPs(Ph-PPh3)-Pd | K3PO4·3H2O, H2O/EtOH, 80 °C | 98% | 0.141 (ref. 7a) |
| 2 | Poly-NHC-2–Pd | K3PO4·3H2O, H2O/EtOH, 80 °C | 99% | 1.737 (ref. 8d) |
| 3 | Pd/SMP-PhPh3 | K3PO4·3H2O, H2O/EtOH, 80 °C | 99% | 2.04 (ref. 27) |
| 4 | HCP-Pd–I | K3PO4, H2O, 80 °C | 95% | 0.123 (ref. 17) |
| 5 | MOPs–Pd–I | K3PO4, H2O/EtOH, 80 °C | 97% | 0.206 (ref. 18) |
| 6 | HCPs-bipy-Pd–I | K2CO3, EtOH, 80 °C | 97% | 0.425 (ref. 28) |
| 7 | HCPs-Pd | NaOH, EtOH, 60 °C | 99% | 16.6 [this work] |
a
TON number was calculated from the reported data.