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. 2020 May 13;10(31):17955–17999. doi: 10.1039/c9ra09554c

Recent studies on accelerated weathering aging test setup and test conditions of different biocomposites and main findinga.

Composites Weathering condition & standard Irradiation intensity & wavelength Chamber environment Test duration Results Ref.
WPCBP/WF/PP UV-340A accelerated weatherometer, ISO 4892-1 0.83 50 °C 15 days WPCBP and WF enhance the retention rate of mechanical prop. of PP after UV exposure 122
Higher amount of WPCBP increases the carbonyl index due to the presence of transition metals in WPCBP which accelerate the photo-aging
Linseed cake/PLA UV light, ISO 4892-3 0.76 W m−2, 340 nm 60 °C 250 and 500 h Incorporation of biofiller accelerates the degradation 123
Hydrolytic degradation on amorphous phase (initial UV aging – 250 h)
Hydrolytic degradation on crystalline phase (later UV aging – 500 h)
SiCO/PLA Xenon lamp, ASTM G155-13 cycle 1 0.35 W m−2 (340 nm) 63 °C, 30% humidity, light and water spray for 18 min 260 and 520 h Tensile properties, thermal stability and rheology decreased after aging, while, % crystallinity increased 124
PF/PP, PALF/PP Mercury pressure lamps 400 watts (300 nm) 60 °C 30, 40, 50 h PF/PP shows better properties retention than PALF/PP after photo-aging due to higher lignin content of PF 116
Wood fibre/PP (bleached and unbleached) with MAPP Fluorescent bulb UVA, ASTM G154-00a 0.68 W m−2 (340 nm) 50 °C, 2 h condensation per cycle 150, 400, 600, 800 and 1000 h Both bleached and unbleached wood fibre composites shows reduction in mechanical prop. After accelerated weathering 56
Reduction in mechanical prop. was due to degradation of lignin, chain scission of PP and deterioration of fibre–matrix interface
Wood flour/PP with MAPP Weather-Ohmeter (xenon arc 3500 W lamp, 60 W m−2, 300–400 nm 60 °C 14 days Recycled of the UV-aged WF/PP were able to recover the initial properties of the WF/PP biocomposites 120
WF/PP, lignin/PP, cellulose/PP QUV accelerated weathering, ASTM G154 0.89 W m−2, at 340 nm 60 °C, 4 h condensation per cycle 960 h Composite containing lignin was more sensitive to photodegradation (from color change results) 125
Lignin/PP showed better retention in flexural strength and modulus, better hydrophobicity and less cracks, on UV-aged surface than PP biocomposites
Starch/WF/PLA with 15% of glycerol Fluorescent lamps, ASTM G154-06 0.89 W m−2, at 340 nm 4 h condensation per cycle 300, 600 and 1200 h Carboxylic acid was formed on the surface after UV-aging 126
Glycerol exhibited stabilize effect on the UV durability of the biocomposites
Lignin/PLA Mercury lamp 39 mW cm−2, 200–700 nm 30 °C, 60% humidity 600 h Free surface energy increased after weathering 115
Lignin/PLA show less reduction in tensile and impact strength than other samples after UV-aging
Mt/PLA (1 mass%) Fluorescent lamps, SAE J2020, ASTM G154-05 and ISO 4892-3 0.49 W m−2, 310 nm 70 °C, 4 h dark condensation per cycle 50, 100, 150 and 200 h PLA nanocomposite with 1 mass% Mt clay showed extremely beneficial effect on the durability performance after accelerated weathering (good mechanical prop. retention) 127
HNT/PLA Fluorescent lamps, cycle-C of the ISO 4892-3 0.49 W m−2, 310 nm 70 °C, 4 h dark condensation per cycle 300 h Intensities of the distinctive IR bands of PLA were decreased after weathering degradation due to photolysis, hydrolysis and chain scission 128
Reinforcing effect of HNT in PLA could compensate the loss in mechanical prop. After aging
TiO2/EVA/PLA Accelerated weathering, ISO 4892/3 NS 60 °C, 8 h irradiation, 4 h humidity condensation per cycle 8–56 cycles Different TiO2 crystal form could affect the degree of photodegradation 129
Rutile TiO2 do not enhance the degradation, but anatase and mixed crystals TiO2 nanoparticles promoted the degradation of the nanocomposites
WF/PP with pigments Accelerated weathering, ASTM G 154 0.89 W m−2, at 340 nm 60 °C, 8 h irradiation, 4 h condensation per cycle 240, 480, 720 and 960 h Incorporation of pigments was proven to be more effective staining method for improving color stability during weathering as compared to the use of dye WF 130
WF/HDPE Accelerated weathering, ASTM G154-12a 0.89 W m−2, at 340 nm 60 °C, 8 h irradiation, 4 h condensation per cycle 500, 1000, 1500, and 2000 h Weathering degradation of the biocomposites is affected by the type of WF 131
A. Mangium/HDPE shows better surface color and properties stability after aging than E. urophylla and P. caribaea/HDPE
ZnO/WF/HDPE UVB lamps, ASTM D4329 313 nm 60 °C, 8 h irradiation, 4 h condensation per cycle 500, 1000 and 1500 h Surface cracks, contact angle changes and mechanical prop. loss were reduced with increasing ZnO content 132
Incorporation of ZnO changed the photodegradation mechanism of the biocomposites
Teakwood sawdust/PBS ASTM-G154 cycle A NS 60 °C, 8 h irradiation, 4 h condensation per cycle 5 cycles, 60 h Tensile modulus increased while flexural properties decreased 112
Loss in mechanical prop. was due to the hydrolytic degradation which induced by the hydrophilicity of lignocellulosic biofibre
Biofibres (Oak, cotton burr and guayule bagasse)/HDPE Accelerated weathering, Fluorescent UV lamps, ASTM G 154 0.85 W m−2, 340 nm 45 °C, UV irradiated for 4 h (60 °C), condensation for 4 h (50 °C) 2200 h Coupling agents helped to retain the mechanical prop. Of biocomposites after UV exposure 133
Biofibres accelerates the UV degradation rate of HDPE
Flax fibre/epoxidized sucrose soyate 40 watt UVA-340 fluorescent lamps 0.5 W m−2 40 °C, 4 h UV and water condensation 1000 h each side The properties of biocomposites reduced after weathering 134
Fibre treatments aid in improving resistance to property degradation after weathering
FDE/PLA, SD/PLA UVA-340 fluorescent lamps 60 °C, 8 h UVA radiation, 4 h condensation 0, 250, 500, 750 and 1000 h Larger extend of mechanical prop. deterioration was observed for FDE/PLA as compared to SD/PLA biocomposites after UV-aging 135
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Abbreviation: WPCBPs: waste-printed circuit boards; WF: wood flour; SiCO: capsicum oleoresin encapsulated porous silica; PF: palm fibre; PALF: pineapple leaf fibres; MAPP: maleated polypropylene; Mt: montmorillonite; HNT: halloysite nanotubes; EVA: ethylene vinyl acetate copolymer; NS: not stated; PBS: poly(butylene succinate); FDE: farm dairy effluent; SD: wood sander dust.