Recent studies on accelerated weathering aging test setup and test conditions of different biocomposites and main findinga.
Composites | Weathering condition & standard | Irradiation intensity & wavelength | Chamber environment | Test duration | Results | Ref. |
---|---|---|---|---|---|---|
WPCBP/WF/PP | UV-340A accelerated weatherometer, ISO 4892-1 | 0.83 | 50 °C | 15 days | WPCBP and WF enhance the retention rate of mechanical prop. of PP after UV exposure | 122 |
Higher amount of WPCBP increases the carbonyl index due to the presence of transition metals in WPCBP which accelerate the photo-aging | ||||||
Linseed cake/PLA | UV light, ISO 4892-3 | 0.76 W m−2, 340 nm | 60 °C | 250 and 500 h | Incorporation of biofiller accelerates the degradation | 123 |
Hydrolytic degradation on amorphous phase (initial UV aging – 250 h) | ||||||
Hydrolytic degradation on crystalline phase (later UV aging – 500 h) | ||||||
SiCO/PLA | Xenon lamp, ASTM G155-13 cycle 1 | 0.35 W m−2 (340 nm) | 63 °C, 30% humidity, light and water spray for 18 min | 260 and 520 h | Tensile properties, thermal stability and rheology decreased after aging, while, % crystallinity increased | 124 |
PF/PP, PALF/PP | Mercury pressure lamps | 400 watts (300 nm) | 60 °C | 30, 40, 50 h | PF/PP shows better properties retention than PALF/PP after photo-aging due to higher lignin content of PF | 116 |
Wood fibre/PP (bleached and unbleached) with MAPP | Fluorescent bulb UVA, ASTM G154-00a | 0.68 W m−2 (340 nm) | 50 °C, 2 h condensation per cycle | 150, 400, 600, 800 and 1000 h | Both bleached and unbleached wood fibre composites shows reduction in mechanical prop. After accelerated weathering | 56 |
Reduction in mechanical prop. was due to degradation of lignin, chain scission of PP and deterioration of fibre–matrix interface | ||||||
Wood flour/PP with MAPP | Weather-Ohmeter (xenon arc | 3500 W lamp, 60 W m−2, 300–400 nm | 60 °C | 14 days | Recycled of the UV-aged WF/PP were able to recover the initial properties of the WF/PP biocomposites | 120 |
WF/PP, lignin/PP, cellulose/PP | QUV accelerated weathering, ASTM G154 | 0.89 W m−2, at 340 nm | 60 °C, 4 h condensation per cycle | 960 h | Composite containing lignin was more sensitive to photodegradation (from color change results) | 125 |
Lignin/PP showed better retention in flexural strength and modulus, better hydrophobicity and less cracks, on UV-aged surface than PP biocomposites | ||||||
Starch/WF/PLA with 15% of glycerol | Fluorescent lamps, ASTM G154-06 | 0.89 W m−2, at 340 nm | 4 h condensation per cycle | 300, 600 and 1200 h | Carboxylic acid was formed on the surface after UV-aging | 126 |
Glycerol exhibited stabilize effect on the UV durability of the biocomposites | ||||||
Lignin/PLA | Mercury lamp | 39 mW cm−2, 200–700 nm | 30 °C, 60% humidity | 600 h | Free surface energy increased after weathering | 115 |
Lignin/PLA show less reduction in tensile and impact strength than other samples after UV-aging | ||||||
Mt/PLA (1 mass%) | Fluorescent lamps, SAE J2020, ASTM G154-05 and ISO 4892-3 | 0.49 W m−2, 310 nm | 70 °C, 4 h dark condensation per cycle | 50, 100, 150 and 200 h | PLA nanocomposite with 1 mass% Mt clay showed extremely beneficial effect on the durability performance after accelerated weathering (good mechanical prop. retention) | 127 |
HNT/PLA | Fluorescent lamps, cycle-C of the ISO 4892-3 | 0.49 W m−2, 310 nm | 70 °C, 4 h dark condensation per cycle | 300 h | Intensities of the distinctive IR bands of PLA were decreased after weathering degradation due to photolysis, hydrolysis and chain scission | 128 |
Reinforcing effect of HNT in PLA could compensate the loss in mechanical prop. After aging | ||||||
TiO2/EVA/PLA | Accelerated weathering, ISO 4892/3 | NS | 60 °C, 8 h irradiation, 4 h humidity condensation per cycle | 8–56 cycles | Different TiO2 crystal form could affect the degree of photodegradation | 129 |
Rutile TiO2 do not enhance the degradation, but anatase and mixed crystals TiO2 nanoparticles promoted the degradation of the nanocomposites | ||||||
WF/PP with pigments | Accelerated weathering, ASTM G 154 | 0.89 W m−2, at 340 nm | 60 °C, 8 h irradiation, 4 h condensation per cycle | 240, 480, 720 and 960 h | Incorporation of pigments was proven to be more effective staining method for improving color stability during weathering as compared to the use of dye WF | 130 |
WF/HDPE | Accelerated weathering, ASTM G154-12a | 0.89 W m−2, at 340 nm | 60 °C, 8 h irradiation, 4 h condensation per cycle | 500, 1000, 1500, and 2000 h | Weathering degradation of the biocomposites is affected by the type of WF | 131 |
A. Mangium/HDPE shows better surface color and properties stability after aging than E. urophylla and P. caribaea/HDPE | ||||||
ZnO/WF/HDPE | UVB lamps, ASTM D4329 | 313 nm | 60 °C, 8 h irradiation, 4 h condensation per cycle | 500, 1000 and 1500 h | Surface cracks, contact angle changes and mechanical prop. loss were reduced with increasing ZnO content | 132 |
Incorporation of ZnO changed the photodegradation mechanism of the biocomposites | ||||||
Teakwood sawdust/PBS | ASTM-G154 cycle A | NS | 60 °C, 8 h irradiation, 4 h condensation per cycle | 5 cycles, 60 h | Tensile modulus increased while flexural properties decreased | 112 |
Loss in mechanical prop. was due to the hydrolytic degradation which induced by the hydrophilicity of lignocellulosic biofibre | ||||||
Biofibres (Oak, cotton burr and guayule bagasse)/HDPE | Accelerated weathering, Fluorescent UV lamps, ASTM G 154 | 0.85 W m−2, 340 nm | 45 °C, UV irradiated for 4 h (60 °C), condensation for 4 h (50 °C) | 2200 h | Coupling agents helped to retain the mechanical prop. Of biocomposites after UV exposure | 133 |
Biofibres accelerates the UV degradation rate of HDPE | ||||||
Flax fibre/epoxidized sucrose soyate | 40 watt UVA-340 fluorescent lamps | 0.5 W m−2 | 40 °C, 4 h UV and water condensation | 1000 h each side | The properties of biocomposites reduced after weathering | 134 |
Fibre treatments aid in improving resistance to property degradation after weathering | ||||||
FDE/PLA, SD/PLA | UVA-340 fluorescent lamps | 60 °C, 8 h UVA radiation, 4 h condensation | 0, 250, 500, 750 and 1000 h | Larger extend of mechanical prop. deterioration was observed for FDE/PLA as compared to SD/PLA biocomposites after UV-aging | 135 |
Abbreviation: WPCBPs: waste-printed circuit boards; WF: wood flour; SiCO: capsicum oleoresin encapsulated porous silica; PF: palm fibre; PALF: pineapple leaf fibres; MAPP: maleated polypropylene; Mt: montmorillonite; HNT: halloysite nanotubes; EVA: ethylene vinyl acetate copolymer; NS: not stated; PBS: poly(butylene succinate); FDE: farm dairy effluent; SD: wood sander dust.