Skip to main content
. 2020 May 21;10(33):19501–19505. doi: 10.1039/d0ra03618h

Immobilised oxidases are used to facilitate oxidation of a number of substrates with the same supported catalysta.

graphic file with name d0ra03618h-u1.jpg
Day GOase M3–5 AcCO6 MAO-N D9
1 graphic file with name d0ra03618h-u2.jpg graphic file with name d0ra03618h-u3.jpg graphic file with name d0ra03618h-u4.jpg
2 graphic file with name d0ra03618h-u5.jpg graphic file with name d0ra03618h-u6.jpg graphic file with name d0ra03618h-u7.jpg
3 graphic file with name d0ra03618h-u8.jpg graphic file with name d0ra03618h-u9.jpg graphic file with name d0ra03618h-u10.jpg
4 graphic file with name d0ra03618h-u11.jpg graphic file with name d0ra03618h-u12.jpg graphic file with name d0ra03618h-u13.jpg
a

The same samples of immobilised GOase M3–5, AcCO6 and MAO-N D9 were used to sequentially oxidise a number of substrates. Conversions for GOase and AcCO6 were determined by NMR and GC respectively. Conversion for MAO-N were determined for the oxidation of the (S)-enantiomer of the racemic substrate (see ESI for reaction conditions).