Thermodynamic parameters for the adsorption of acridinium derivatives (compound 1 (ClO4− and Cl−) and compound 2 (ClO4− and Cl−)) on SSA.
| Compound | Counterion | ΔG/kJ mol−1 | ΔH/kJ mol−1 | ΔS/kJ mol−1 K−1 | −TΔS/kJ mol−1 | ||||
|---|---|---|---|---|---|---|---|---|---|
| 293 K | 298 K | 303 K | 308 K | 313 K | 298 K | ||||
| 1 | ClO4− | −33.6 | −33.8 | −34.5 | −34.7 | −35.4 | −7.82 | 0.088 | −25.9 |
| 1 | Cl− | −34.5 | −34.8 | −35.3 | −35.7 | −36.0 | −11.3 | 0.079 | −23.5 |
| 2 | ClO4− | −35.6 | −36.0 | −36.3 | −36.5 | −36.9 | −16.7 | 0.064 | −18.8 |
| 2 | Cl− | −36.7 | −36.6 | −37.0 | −36.9 | −37.6 | −24.6 | 0.041 | −12.0 |