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. 2020 Jun 4;10(36):21360–21368. doi: 10.1039/d0ra03158e

Thermodynamic parameters for the adsorption of acridinium derivatives (compound 1 (ClO4 and Cl) and compound 2 (ClO4 and Cl)) on SSA.

Compound Counterion ΔG/kJ mol−1 ΔH/kJ mol−1 ΔS/kJ mol−1 K−1 TΔS/kJ mol−1
293 K 298 K 303 K 308 K 313 K 298 K
1 ClO4 −33.6 −33.8 −34.5 −34.7 −35.4 −7.82 0.088 −25.9
1 Cl −34.5 −34.8 −35.3 −35.7 −36.0 −11.3 0.079 −23.5
2 ClO4 −35.6 −36.0 −36.3 −36.5 −36.9 −16.7 0.064 −18.8
2 Cl −36.7 −36.6 −37.0 −36.9 −37.6 −24.6 0.041 −12.0