| Free base meso-arylporphyrins | |||||||
|---|---|---|---|---|---|---|---|
| Compound | λ max (nm) (ε × 10−3 L mmol−1 cm−1) | E gap-opt (eV) | Ref. | ||||
| Soret band | Q bands | ||||||
| H2(TPP)a | 416(419) | 513(20) | 550(20) | 590(6) | 646(6) | 1.89 | 26 |
| H2(TTP)b | 420 | 516 | 552 | 594 | 640 | 1.86 | 27 |
| H2(TPBP)c | 420(513) | 516(17) | 552(7) | 591(5) | 646(4) | 1.82 | 4 |
| H2(TEBOP)d | 422(295) | 517(9) | 554(8) | 593(5) | 651(7) | 1.85 | 18 |
| H2(TAzP-HVP) 4a | 420(565) | 517(42) | 554(19) | 593(15) | 650(13) | 1.88 | This work |
| H2(TAzP-ClVP) 4b | 422(551) | 518(35) | 555(26) | 594(15) | 651(17) | 1.87 | This work |
| H2(TAzP-IVP) 4c | 424(576) | 520(46) | 555(29) | 595(24) | 652(18) | 1.86 | This work |
a
TPP = meso-tetraphenylporphyrinato.
b
TTP = meso-tetratolylporphyrinato.
c
TPBP = meso-tetrakis-[4-(benzoyloxy)phenyl]porphyrinato.
d
TEBOP = meso-tetrakis(ethyl-4(4-butyryl)oxyphenyl)porphyrinato.
e
TMP = meso-tetrakis(2,4,6-trimethylphenyl)porphyrinato.