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. 2020 Jun 22;10(40):23543–23553. doi: 10.1039/d0ra03483e

Optimization of ethylbenzene oxidation reaction.

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Entry Catalyst [mg, mol%] Solvent O2/Ar TBHP [equiv.] T [h] Conv. [%] Sel. [%] to A
1 — Solvent free O2 2 8 4 97
2 30, 39 Solvent free O2 2 8 53 93
3 40, 52 Solvent free O2 2 8 >99 99
4 50, 65 Solvent free O2 2 8 92 87
5 40, 52 Solvent free O2 1 8 75 100
6 40, 52 Solvent free O2 3 8 79 96
7 40, 52 Solvent free Ar 2 8 73 93
8 40, 52 CH3CN O2 2 8 71 50
9 40, 52 CH3CN/H2O O2 2 8 74 90
10 40, 52 H2O O2 2 8 69 98