| 1 (ref. 29) |
MnWO4 nanobars (0.01 g, 5 wt%) |
Toluene (0.2 mL), CH3CN (8 mL), H2O2 (3 equiv.), T = 80 °C, time = 24 h |
60 |
Benzaldehyde |
| 2 (ref. 30) |
Mn0.3Zr0.7O2
|
Toluene (1000 ppm), 20% O2 balanced by N2, total flow rate = 50 mL min−1, weight hourly space velocity = 60 000 mL gcat−1 h−1, T = 235 °C, in a fixed-bed quartz tubular reactor |
90 |
Maleic anhydride |
| 3 (ref. 31) |
Cu functionalized nano-crystalline ZSM-5 (1 g, 0.4 wt%) |
Toluene (25 mL), deionized water (25 mL), H2O2 (25 mL), T = 180 °C, time = 4 h, in a PARR autoclave reactor, N2 gas pressure = 5.0 bar |
96 |
Benzoic acid |
| 4 (ref. 32) |
Pd–Ag@CeO2 (100 mg) |
Toluene (500 ppm), 20% O2 balanced with N2, T = 88 °C, total gas flow rate = 33.3 mL min−1, visible light intensity = 160 mW cm−2
|
50 |
Not identified |
| 5 (ref. 33) |
Polystyrene grafted vanadium Schiff base complex (30 mg, 6.58 wt%) |
Toluene (5 mmol), CH3CN (10 mL), H2O2 (15 mmol), T = 65 °C, time = 6 h |
79 |
Benzaldehyde |
| 6 (ref. 34) |
Pt28 subnanocatalyst (10 mg, 0.216 wt%) |
Toluene (2 mL), O2 (1 MPa), T = 160 °C, time = 15 h, in an autoclave reactor |
1000 μmol product |
Benzoic acid |
| 7 (ref. 35) |
MnTPPCl (1.0 × 10−3 mmol) |
Toluene (5 mmol), cyclohexene (3 mmol), CH3CN (10 mL), O2 (1.2 MPa), T = 160 °C, time = 4 h |
13 |
Benzoic acid |
| 8 (ref. 36) |
Fe3O4@SiO2-APTES-MnLGDC (40 mg, 2 mol%) |
Toluene (1 mmol), solvent free, TBHP (4 equiv., 70%), T = 60 °C, time = 20 h |
71 |
Benzoic acid |
|
This work
|
VO
2+
@SiO
2
@Fe
3
O
4
(40 mg, 52 mol%)
|
Toluene (1 mmol), H
2
O (0.5 mL), O
2
balloon, T = RT, time = 10 h
|
99
|
Benzyl alcohol
|
|
Toluene (1 mmol), H
2
O (0.5 mL), Ar, TBHP (2 equiv., 70%), T = RT, time = 8 h
|
99
|
Benzoic acid
|
