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. 2020 Jul 10;10(44):26142–26150. doi: 10.1039/d0ra04064a

Aerobic oxidation of various alcohols catalyzed by Fe3O4@Cu2O nanomateriala.

Entry Substrate Product Selectivity (%) Yieldb (%)
1 graphic file with name d0ra04064a-u1.jpg graphic file with name d0ra04064a-u2.jpg >99 >99
2 graphic file with name d0ra04064a-u3.jpg graphic file with name d0ra04064a-u4.jpg >99 >99
3 graphic file with name d0ra04064a-u5.jpg graphic file with name d0ra04064a-u6.jpg >99 92
4 graphic file with name d0ra04064a-u7.jpg graphic file with name d0ra04064a-u8.jpg >99 96
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12 graphic file with name d0ra04064a-u23.jpg graphic file with name d0ra04064a-u24.jpg >99 14
13 graphic file with name d0ra04064a-u25.jpg graphic file with name d0ra04064a-u26.jpg 16.5 9
14 graphic file with name d0ra04064a-u27.jpg graphic file with name d0ra04064a-u28.jpg >99 5
15 graphic file with name d0ra04064a-u29.jpg graphic file with name d0ra04064a-u30.jpg >99 3
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a

Reaction conditions: alcohol (5 mmol), Fe3O4@Cu2O (15 mg), TEMPO (0.25 mmol, 39.1 mg), NMI (0.25 mmol, 20 mg), CH3CN (5 mL), 25 °C, 18 h.

b

Confirmed by GC-MS analysis.