Aerobic oxidation of various alcohols catalyzed by Fe3O4@Cu2O nanomateriala.
| Entry | Substrate | Product | Selectivity (%) | Yieldb (%) |
|---|---|---|---|---|
| 1 |
|
|
>99 | >99 |
| 2 |
|
|
>99 | >99 |
| 3 |
|
|
>99 | 92 |
| 4 |
|
|
>99 | 96 |
| 5 |
|
|
>99 | >99 |
| 6 |
|
|
>99 | >99 |
| 7 |
|
|
>99 | >99 |
| 8 |
|
|
>99 | >99 |
| 9 |
|
|
>99 | >99 |
| 10 |
|
|
>99 | >99 |
| 11 |
|
|
>99 | >99 |
| 12 |
|
|
>99 | 14 |
| 13 |
|
|
16.5 | 9 |
| 14 |
|
|
>99 | 5 |
| 15 |
|
|
>99 | 3 |
| 16 |
|
|
— | — |
a
Reaction conditions: alcohol (5 mmol), Fe3O4@Cu2O (15 mg), TEMPO (0.25 mmol, 39.1 mg), NMI (0.25 mmol, 20 mg), CH3CN (5 mL), 25 °C, 18 h.
b
Confirmed by GC-MS analysis.