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. 2020 Jul 7;10(43):25586–25601. doi: 10.1039/d0ra03869e

Sorption isotherm models for MO uptake by An/CNT composite.

Isotherm Model Linear form Parameters Ref.
Langmuir Inline graphic, RL = 1/(1 + bC0), RL > 1 (unfavorable adsorption), RL = 1 (linear adsorption), 0 < RL < 1 (favorable adsorption), RL = 0 (irreversible adsorption) C e (mg L−1): equilibrium concentration of the residual MO in the solution 56 and 57
q e (mg g−1): removed amount of MO at equilibrium
q max (mg g−1): maximum adsorption capacity
b (L mg−1): Langmuir constant
q max = 1/slope
b = slope/intercept
C 0: initial MO concentration
R L: equilibrium parameter of Langmuir equation
Freundlich graphic file with name d0ra03869e-t6.jpg C e (mg L−1): equilibrium concentration of the residual MO in the solution 58
q e (mg g−1): removed amount of MO at equilibrium
K F (mg g−1): MO adsorption capacity
n: heterogeneity factor
k F = 10intercept
1/n = slope
Temkin qe = B ln A + B ln Ce, B = RT/b A (L g−1): Temkin isotherm constant (the equilibrium binding constant corresponding to the maximum binding energy) 59
B (J mol−1): Temkin constant related to heat of sorption
b: Temkin isotherm constant
R: the gas constant (8.314 J mol−1 K−1)
T: the absolute temperature at 298 K
A = EXP(intercept/slope)
b = slope