Thermodynamic parameters for F− ions adsorption on G, GL-CS/G, EDTA-GL-CS/G, SDS-CS/G and CTAB-CS/G adsorbents.
Adsorbent | T (K) | ΔH0 (kJ mol−1) | ΔS0 (kJ (mol k)−1) | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
K c at different K temperatures | ΔG0 (kJ mol−1) at different K temperatures | |||||||||||
298 | 303 | 308 | 313 | 318 | 298 | 303 | 308 | 313 | 318 | |||
G | 21.99 | 21.85 | 21.86 | 21.22 | 21.02 | −7.66 | −7.77 | −7.90 | −7.95 | −8.05 | −1.86 | 0.019 |
GL-CS/G | 120.3 | 106.5 | 100.9 | 96.66 | 95.95 | −11.9 | −11.8 | −11.8 | −11.9 | −12.1 | −8.74 | 0.013 |
EDTA-GL-CS/G | 504.8 | 498.8 | 454.2 | 452.7 | 446.9 | −15.4 | −15.7 | −15.7 | −15.9 | −16.1 | −5.38 | 0.033 |
SDS-CS/G | 176.0 | 175.7 | 168.8 | 161.4 | 160.3 | −12.8 | −13.0 | −13.1 | −13.2 | −13.4 | −4.28 | 0.028 |
CTAB-CS/G | 318.1 | 315.4 | 304.9 | 295.9 | 298.7 | −14.3 | −14.5 | −14.6 | −14.8 | −15.1 | −2.99 | 0.037 |