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. 2020 Jul 10;10(44):26078–26089. doi: 10.1039/d0ra04215c

The results of fitting of the impedance spectra obtained at cMo = 0 and 100 mM using EECs from Fig. 6: S is the residual sum of squares and indicate the quality of the fit; Rs is the solution resistance; Tdl and αdl are parameters of CPEdl representing the electrical double layer; Rct is the charge-transfer resistance; the resistance R2 and the constant phase element CPE2 with parameters T2 and α2 correspond to adsorption process, R1 and the inductance L1 are related to liberation of hydrogen bubbles; uncertainties of the fitted parameters, obtained from Zview, are given in brackets.

Conditions S R s Ω cm2 T dl μF sα−1·cm−2 α dl R ct Ω cm2 R 1 Ω cm2 L 1 H cm2 T 2 mF sα−1·cm−2 α2 R 2 Ω cm2
c Mo = 0 mM, η = 0 mV, stagnant solution 0.04 9(1) 829(12) 0.88(0.01) 25(1) 161(18) 2015(452) 84.5(1.6) 0.97(0.02) 12(1)
c Mo = 0 mM, η = 0 mV, agitated solution 0.04 9(1) 971(16) 0.87(0.01) 22(1) 88(9) 1236(221) 79.1(1.5) 0.92(0.02) 13(1)
c Mo = 100 mM, η = 0 mV, stagnant solution 0.12 8(1) 39(1) 0.86(0.01) 1210(7) N.A. N.A. 3549(125) 0.94(0.02) 955(25)
c Mo = 100 mM, η = +100 mV, stagnant solution 0.05 7(1) 50(1) 0.83(0.01) 1240(7) N.A. N.A. 1572(21) 0.81(0.01) 4076(95)
c Mo = 100 mM, η = 0 mV, stagnant solution 0.11 7(1) 66(1) 0.84(0.01) 620(4) N.A. N.A. 6589(236) 0.92(0.02) 496(17)
c Mo = 100 mM, η = −100 mV, stagnant solution 0.12 7(1) 84(1) 0.85(0.01) 53(1) 945(107) 5720(797) N.A. N.A. N.A.