Absorption in film and emission in film, powder and crystalline.
| Compounds | Emission in powder | Absorption in film λmaxe (nm) | Emission in film | Emission in crystalline λmaxf (nm) | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| λ max a (nm) | Life timeb (ns) | QYc (%) | k r d (107 s−1) | k nr d (107 s−1) | λ max f (nm) | Life timeb (ns) | QYc (%) | k r d (107 s−1) | k nr d (107 s−1) | |||
| 1 | 450 | 4.34 | 56.55 | 13.0 | 10.0 | 364 | 467 | 5.04 | 31.55 | 6.3 | 13.6 | 468 |
| 2 | 495 | 2.86 | 49.91 | 17.5 | 17.5 | 410 | 509 | 3.00 | 26.06 | 8.7 | 24.6 | 491 |
| 3 | 559 | 5.44 | 28.03 | 5.2 | 13.2 | 429 | 555 | 4.84 | 25.99 | 5.4 | 15.3 | 539 |
| 4 | 540 | 15.04 | 27.51 | 1.8 | 4.8 | 412 | 506 | 0.48(60.8%) | 20.86 | 8.0 | 30.2 | 532 |
| 3.94(39.2%) | ||||||||||||
| 5 | 617 | 2.45 | 3.08 | 1.3 | 39.6 | 413 | —g | —g | —g | — g | —g | —h |
| 6 | 460 | 2.34 | 15.21 | 6.5 | 36.2 | 388 | 467 | 1.31 | 32.84 | 25.1 | 51.3 | —h |
| 7 | 488 | 4.88 | 31.70 | 6.5 | 14.0 | 416 | 536 | 3.34 | 35.70 | 10.7 | 19.3 | —h |
| 8 | 558 | 7.61 | 17.92 | 2.4 | 10.8 | 430 | 543 | 7.4 | 11.35 | 1.5 | 12.0 | —h |
| 9 | 568 | 9.58 | 11.33 | 1.2 | 9.3 | 455 | 540 | 0.65(6.5%) | 17.96 | 4.0 | 18.2 | —h |
| 5.28(93.5%) | ||||||||||||
| 10 | —g | —g | —g | —g | —g | —g | —g | —g | —g | —g | —g | —h |
Excited at 380 nm (9), 400 nm (5) and 365 nm (1–4, 6–8 and 10).
According to fluorescence decay traces.
Quantum yields were obtained from an integrating sphere.
Calculated by QY = τkr = kr/(kr + knr).
Films were prepared by spin-coating a dilute DCM solution on a quartz plate.
Excited at 365 nm.
Emission is too weak to be detected.
No single crystal was obtained.