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. 2020 Aug 17;10(51):30297–30303. doi: 10.1039/d0ra05701k

Absorption in film and emission in film, powder and crystalline.

Compounds Emission in powder Absorption in film λmaxe (nm) Emission in film Emission in crystalline λmaxf (nm)
λ max a (nm) Life timeb (ns) QYc (%) k r d (107 s−1) k nr d (107 s−1) λ max f (nm) Life timeb (ns) QYc (%) k r d (107 s−1) k nr d (107 s−1)
1 450 4.34 56.55 13.0 10.0 364 467 5.04 31.55 6.3 13.6 468
2 495 2.86 49.91 17.5 17.5 410 509 3.00 26.06 8.7 24.6 491
3 559 5.44 28.03 5.2 13.2 429 555 4.84 25.99 5.4 15.3 539
4 540 15.04 27.51 1.8 4.8 412 506 0.48(60.8%) 20.86 8.0 30.2 532
3.94(39.2%)
5 617 2.45 3.08 1.3 39.6 413 g g g g g h
6 460 2.34 15.21 6.5 36.2 388 467 1.31 32.84 25.1 51.3 h
7 488 4.88 31.70 6.5 14.0 416 536 3.34 35.70 10.7 19.3 h
8 558 7.61 17.92 2.4 10.8 430 543 7.4 11.35 1.5 12.0 h
9 568 9.58 11.33 1.2 9.3 455 540 0.65(6.5%) 17.96 4.0 18.2 h
5.28(93.5%)
10 g g g g g g g g g g g h
a

Excited at 380 nm (9), 400 nm (5) and 365 nm (1–4, 6–8 and 10).

b

According to fluorescence decay traces.

c

Quantum yields were obtained from an integrating sphere.

d

Calculated by QY = τkr = kr/(kr + knr).

e

Films were prepared by spin-coating a dilute DCM solution on a quartz plate.

f

Excited at 365 nm.

g

Emission is too weak to be detected.

h

No single crystal was obtained.