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. 2020 Aug 20;10(51):30858–30869. doi: 10.1039/d0ra05271j

The assignment of modes based on wavenumber.

Wavenumber (cm−1) Approximate description
755 C8–H22 Indole ring Strong In-plane Stretch
C12–H25 Medium In-plane Stretch
C5–H20
N6–H21 In-plane Stretch
840 H23–C9 Ring Strong
H22–C8
H20–C5 Rock Out-of-plane
946 H22–C8 Ring Strong
H23–C9 Rock Out-of-plane
1208 H24–O11 Rock Strong In-plane
H22–C8–H23–C9 Scissor In-plane
1312 C3–H19–H18 Twist Strong
H16–C2–H17 Twist
H20–C5 Rock In-plane
1360 H16–C2–H17 Twist Strong
H20–C5 Rock In-plane
1433 H16–C2–H17 Wag Strong
H18–C3–H19 Wag Medium
1542 H16–C2–H17 Scissor Strong