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. 2020 Aug 27;10(52):31662–31669. doi: 10.1039/d0ra05374k

Extension of reaction substrate.

graphic file with name d0ra05374k-u2.jpg
Entrya Nucleophiles Product Yieldb (%) M.P./°C
Found Report (Lit)
1 graphic file with name d0ra05374k-u3.jpg graphic file with name d0ra05374k-u4.jpg 98 140–142 142–143 (ref. 37)
2 graphic file with name d0ra05374k-u5.jpg graphic file with name d0ra05374k-u6.jpg 88 158–160 134–135 (ref. 29)
3 graphic file with name d0ra05374k-u7.jpg graphic file with name d0ra05374k-u8.jpg 91 189–191 187–189 (ref. 29)
4 graphic file with name d0ra05374k-u9.jpg graphic file with name d0ra05374k-u10.jpg 98 176–178 183–191 (ref. 37)
5 graphic file with name d0ra05374k-u11.jpg graphic file with name d0ra05374k-u12.jpg 88 154–155 142–145 (ref. 37)
6 graphic file with name d0ra05374k-u13.jpg graphic file with name d0ra05374k-u14.jpg 90 168–169 184–186 (ref. 37)
7 graphic file with name d0ra05374k-u15.jpg graphic file with name d0ra05374k-u16.jpg 93 151–153 145–147 (ref. 37)
8 graphic file with name d0ra05374k-u17.jpg graphic file with name d0ra05374k-u18.jpg 93 169–172 155–158 (ref. 37)
9 graphic file with name d0ra05374k-u19.jpg graphic file with name d0ra05374k-u20.jpg 95 158–160 —
10 graphic file with name d0ra05374k-u21.jpg graphic file with name d0ra05374k-u22.jpg 92 193–195 186–187 (ref. 29)
11 graphic file with name d0ra05374k-u23.jpg graphic file with name d0ra05374k-u24.jpg 91 193–194 176–178 (ref. 37)
12 graphic file with name d0ra05374k-u25.jpg graphic file with name d0ra05374k-u26.jpg 88 110–112 113–119 (ref. 36)
13 graphic file with name d0ra05374k-u27.jpg graphic file with name d0ra05374k-u28.jpg 91 136–138 139–141 (ref. 37)
14 graphic file with name d0ra05374k-u29.jpg graphic file with name d0ra05374k-u30.jpg 90 184–186 —
15 graphic file with name d0ra05374k-u31.jpg graphic file with name d0ra05374k-u32.jpg 92 74–76 77–80 (ref. 31)
16 graphic file with name d0ra05374k-u33.jpg graphic file with name d0ra05374k-u34.jpg 95 189–191 192 °C (ref. 36)
17 Me3SiN3 graphic file with name d0ra05374k-u35.jpg 90 White oil White oil36
a

Reaction conditions: xanthen-9-ol (0.5 mmol), indoles (0.5 mmol), ionic liquid (0.1 eq.), 50 °C, 4 h.

b

Isolated yields.