Solvent-free and open-air reaction between crystalline cellulose and different molten organic acids.
Entry | Organic acid | Melting point (°C) | Yield in bio-oil (%) | Yield in cellulose ester (%) |
---|---|---|---|---|
1a | Oxalic acid dihydrate | 104–106 | — | 80 |
2 | Benzoic acid | 121–123 | — | — |
3 | Adipic acid | 151–154 | — | 90–100 |
4 | Citric acid | 152–155 | 60–80 | 40–20 |
5b | l(+)Tartaric acid | 168–170 | — | — |
6b | Succinic acid | 185–188 | — | — |
See ref. 33.
Only decomposition products (biochar).